Enzymatic synthesis of 2,5-furandicarboxylic acid-based semi-aromatic polyamides: enzymatic polymerization kinetics, effect of diamine chain length and thermal properties
نویسندگان
چکیده
Department of Polymer Chemistry, Zern University of Groningen, Nijenborgh 4, E-mail: [email protected]; Tel: +31-50 363 68 Dutch Polymer Institute (DPI), P.O. Box 90 † Electronic supplementary information ( crude PA8F from the enzymatic kinetics st crude PA8F determined by SEC, molec the puried FDCA-based semi-aromatic obtained FDCA-based semi-aromatic pol DSC curves of the obtained FDCA-based 10.1039/c6ra14585j ‡ Equal contribution. Cite this: RSC Adv., 2016, 6, 67941
منابع مشابه
Synthesis and Characterization of Novel Photoactive Poly(ether-amide)s Based on Highly Substituted Phenanthrimidazole
A new aromatic diamine monomer containing ether linkage based on the phenanthrimidazole ring, 1,1´-(4,4´- oxy bis(1,4-phenylene))bis(2-(4-aminophenyl)-1H-phenanthro[9,10-d]imidazole) was synthesized through four-components condensation of 4,4´-diamino diphenyl ether, 4-nitrobenzaldehyde, phenanthrene-9,10-dione and ammonium acetate in presence of acetic acid, followed by palladi...
متن کاملNew Thermally Stable Aromatic Polyimides Based on Aromatic Diamine 2,5-Bis(3-amino-4-methyl benzene)-1,3,4-oxadiazole (BAMO): Synthesis and Characterization
In current study, the synthesis and characterization of novel thermally stable polyimides (PIs) containing an 1,3,4-oxadiazole moiety based on a diamine, i.e. 2,5-bis(3-amino-4-methyl benzene)-1,3,4-oxadiazole (BAMO), have been reported. The polymers were characterized using FT-IR and elemental analysis (CHN). Thermal and mechanical behaviours of the prepared PIs were studied by thermo-gravimet...
متن کاملSynthesis and characterization of new polyamides derived from alanine and valine derivatives
UNLABELLED BACKGROUND Many efforts have been recently devoted to design, investigate and synthesize biocompatible, biodegradable polymers for applications in medicine for either the fabrication of biodegradable devices or as drug delivery systems. Many of them consist of condensation of polymers having incorporated peptide linkages susceptible to enzymatic cleavage. Polyamides (PAs) containi...
متن کاملSelf-sustained enzymatic cascade for the production of 2,5-furandicarboxylic acid from 5-methoxymethylfurfural
Background 2,5-Furandicarboxylic acid is a renewable building block for the production of polyfurandicarboxylates, which are biodegradable polyesters expected to substitute their classical counterparts derived from fossil resources. It may be produced from bio-based 5-hydroxymethylfurfural or 5-methoxymethylfurfural, both obtained by the acidic dehydration of biomass-derived fructose. 5-Methoxy...
متن کاملSynthesis and Characterization of Polyamide Containing Maleimide Pendant Group
A series of new polyamides containing maleimide pendant group were prepared by low temperature polycondensation of 5-(4-(2,5-dioxo-2H-pyrrol-1(5H)-yl)benzamido)isophthaloyl chloride as a new monomer with various aromatic diamines in NMP. Monomer and polymers structures were identified through FT-IR, 1H-NMR and elemental analysis. Obtained polymers were soluble in polar solvents and non solu...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2016